C.I. ACID GREEN 3

A.F. GREEN NO. 1
ACID GREEN
ACID GREEN 2G
ACID GREEN 3
ACID GREEN B
ACID GREEN G
ACID GREEN L
ACID GREEN S
ACID LEATHER GREEN 3G
ACID LEATHER GREEN F
ACIDAL GREEN G
ACILAN GREEN B
AMACID GREEN B
AMMONIUM, ETHYL(4-(P-(ETHYL(M-SULFOBENZYL)AMINO) -ALPHA-PHENYLBENZYLIDENE)- 2,5-CYCLOHEXADIEN-1- YLIDENE)(M-SULFOBENZYL)-, HYDROXIDE, INNER SALT,
SODIUM SALT
BENZENEMETHANAMINIUM, N-ETHYL-N-(4-((4-(ETHYL((3- SULFOPHENYL)METHYL)AMINO)PHENYL)PHENYLMETH-YLENE) -2,5- CYCLOHEXADIEN-1-YLIDENE)-3-SULFO-,
HYDROXIDE, INNER SALT, SODIUM SALT
BENZENEMETHANAMINIUM, N-ETHYL-N-(4-((4-(ETHYL((3- SULFOPHENYL)METHYL)AMINO)PHENYL)PHENYLMETHYLENE) -2,5-CYCLOHEXADIEN-1-YLIDENE)-3-SULFO-,
HYDROXIDE, INNER SALT, SODIUM SALT
BENZENEMETHANAMINIUM, N-ETHYL-N-(4-((4-(ETHYL((3- SULFOPHENYL)METHYL)AMINO)PHENYL)PHENYLMETHYLENE) -2,5-CYCLOHEXADIEN-1-YLIDENE)-3-SULFO-, INNER
SALT, SODIUM SALT
BRILLIANT GREEN 3EMBL
BUCACID GUINEA GREEN BA
C.I. ACID GREEN 003
C.I. ACID GREEN 1
C.I. ACID GREEN 3
C.I. ACID GREEN 3, MONOSODIUM SALT
C.I. ACID GREEN 3, SODIUM SALT
C.I. FOOD GREEN 1
CALCOCID GREEN G
N-ETHYL-N-(4-((4-(ETHYL((3-SULFOPHENYL)METHYL) AMINO)PHENYL)PHENYLMETHYLENE)-2,5-CYCLOHEXADIEN- 1-YLIDENE)-3-SULFOBENZENEMETHANAMINIUM INNER
SALT, SODIUM SALT
N-ETHYL-N-(4-((4-(ETHYL((3-SULFOPHENYL)METHYL)- AMINO)PHENYL)PHENYL-METHYLENE)-2,5-CYCLOHEXADIEN- 1-YLIDENE)-3-SULFOBENZENEMETHANAMINIUM HYDROXIDE
INNER SALT, SODIUM SALT
FD & C GREEN 1
FD AND C GREEN NO. 1
FD AND C GREEN NUMBER 1
FDC GREEN 1
FENAZO GREEN L
FOOD GREEN 1
GUINEA GREEN
GUINEA GREEN B
GUINEA GREEN BA
HIDACID EMERALD GREEN
HISPACID GREEN GB
HYDROGEN(ETHYL)(4-(.ALPHA.-(4-(ETHYL(3- SULPHONATOBENZYL)AMINO)PHENYL)BENZYLIDENE) CYCLOHEXA-2,5-DIEN-1-YLIDENE)
(3-SULPHONATOBENZYL)AMMONIUM, SODIUM SALT
INTRACID GREEN F
JAPAN GREEN 1
KITON GREEN F
KITON GREEN FC
LEATHER GREEN B
LISSAMINE GREEN G
MERANTINE GREEN G
MONOSODIUM SALT OF 4-(4-(N-ETHYL-PARA- SULFOBENZYLAMINO)DIPHENYLMETHYLENE)-(1-(N-ETHYL- N-PARA-SULFONIUMBENZYL)-DELTA 2,5-CYCLOHEXADIENIMINE)
NAPHTHALENE GREEN G
NAPHTHALENE LAKE GREEN G
NAPHTHALENE LEATHER GREEN G
NERAN BRILLIANT GREEN G
PONTACYL GREEN B
PONTACYL GREEN BL
SULFACID BRILLIANT GREEN 1B
SULPHO GREEN 2B
VONDACID GREEN L
ZELEN KYSELA 3 (CZECH)
ZELEN POTRAVINARSKA 1 (CZECH)

IDENTIFIERS

CAS REGISTRY NUMBER

4680-78-8(Guinea green b)

NIOSH/RTECS NUMBER

BQ4375000

UN/NA NUMBER

Editor's Note: This material is not listed in the Emergency Response Guidebook. Based on the material's physical and chemical properties, toxicity, or chemical group, a guide has been assigned. For additional technical information, contact one of the emergency response telephone numbers listed under Public Safety Measures.

DESIGNATIONS

NSC NUMBER:5016
NSC NUMBER:8684

MOLECULAR FORMULA

C37-H36-N2-O6-S2.Na

ERG GUIDE NUMBER

171-SUBSTANCES (LOW TO MODERATE HAZARD)

SYNONYM REFERENCE

(Ariel GlobalView, 2002;(Ashford, 1994; Budavari, 2000; HSDB , 2002; IARC, 1978; Lewis, 2000; RTECS , 2002)

USES/FORMS/SOURCES

USES

C.I. Acid Green 3 is used to dye leather, silk, wool, paper, and wood; it is also used as a biological stain and indicator. The barium and aluminum salts of C.I. Acid Green 3 serve as pigments (Ashford, 1994; Budavari, 2000; IARC, 1978)
Historically, C.I. Acid Green 3 was utilized as a dye for food, drugs and cosmetics. The United States restricted its use as a color additive in these products in 1966 (refer to 21 CFR 81.30)(Budavari, 2000). Japan also forbade its use in food products in 1979, though it continues to be used there as a colorant for externally applied cosmetics. C.I. Acid Green 3 is now considered unsafe for use in all food products (IARC, 1978).

FORMS

C.I. Acid Green 3 exists as a dull, dark green powder or a bright, crystalline solid (Budavari, 2000; IARC, 1978).
When dissolved in concentrated sulfuric acid, C.I. Acid Green 3 becomes a yellowish solution that, after dilution with water, turns yellowish-red, then green (Budavari, 2000; HSDB , 2002).
In Japan, this compound has the following specifications: 85 percent minimum purity; 4 percent maximum inorganic salt content; 10 percent maximum water content. However, no production has been reported since 1973, when 200 kg were manufactured (HSDB , 2002; IARC, 1978).

SOURCES

C.I. Acid Green 3 does not occur naturally (IARC, 1978).
It is produced commercially by carbonyl condensation/oxidation of N-ethyl-N-phenylbenzylamine-3-sulphonic acid with benzaldehyde (Ashford, 1994). Commercial preparation by condensing benzaldehyde with alpha-(N-ethylanilino)-meta-toluenesulphonic acid, followed by oxidation and conversion to the sodium salt has also been reported (IARC, 1978).

-CLINICAL EFFECTS

GENERAL CLINICAL EFFECTS

At the time of this review, few toxicological data were available about C. I. Acid Green 3. When heated to decomposition, it emits toxic fumes of sodium oxide and oxides of sulfur and nitrogen. Presumably, C. I. Acid Green 3 dust would be irritating to the eyes, nose, and respiratory tract from mechanical action.

Lymphomas, including Hodgkin's disease have been noted in experimental animals. It is considered an equivocal tumorigenic agent by RTECS criteria. The IARC has categorized C. I. Acid Green 3 in Group 3: Unclassifiable as to carcinogenicity to humans.

POTENTIAL HEALTH HAZARDS - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 171 (ERG, 2004)

Inhalation of material may be harmful.
Contact may cause burns to skin and eyes.
Inhalation of Asbestos dust may have a damaging effect on the lungs.
Fire may produce irritating, corrosive and/or toxic gases.
Some liquids produce vapors that may cause dizziness or suffocation.
Runoff from fire control may cause pollution.

ACUTE CLINICAL EFFECTS

C.I. Acid Green 3 may cause skin and eye irritation (HSDB, 1997).

CHRONIC CLINICAL EFFECTS

At the time of this review, no studies of chronically exposed humans were found.

Mild leukopenia, anorexia, and weight loss have been noted in chronically exposed experimental animals (HSDB, 1997). Mild anemia, moderate periportal fatty metamorphosis of the liver, and atrophy of the fat, skeletal muscle, adrenal cortex, lymphatic tissue, and gastric mucosa has been found in chronically exposed experimental animals (Hansen et al, 1966).

C.I. Acid Green 3 may be a skin sensitizer (HSDB, 1997).

-MEDICAL TREATMENT

LIFE SUPPORT

Support respiratory and cardiovascular function.

SUMMARY

FIRST AID - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 171 (ERG, 2004)

Move victim to fresh air.
Call 911 or emergency medical service.
Give artificial respiration if victim is not breathing.
Administer oxygen if breathing is difficult.
Remove and isolate contaminated clothing and shoes.
In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes.
Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.

FIRST AID

INHALATION EXPOSURE -

INHALATION: Move patient to fresh air. Monitor for respiratory distress. If cough or difficulty breathing develops, evaluate for respiratory tract irritation, bronchitis, or pneumonitis. Administer oxygen and assist ventilation as required. Treat bronchospasm with an inhaled beta2-adrenergic agonist. Consider systemic corticosteroids in patients with significant bronchospasm.

DERMAL EXPOSURE -

DECONTAMINATION: Remove contaminated clothing and jewelry and place them in plastic bags. Wash exposed areas with soap and water for 10 to 15 minutes with gentle sponging to avoid skin breakdown. A physician may need to examine the area if irritation or pain persists (Burgess et al, 1999).

EYE EXPOSURE -

DECONTAMINATION: Remove contact lenses and irrigate exposed eyes with copious amounts of room temperature 0.9% saline or water for at least 15 minutes. If irritation, pain, swelling, lacrimation, or photophobia persist after 15 minutes of irrigation, the patient should be seen in a healthcare facility.

ORAL EXPOSURE -

Because of the potential for gastrointesinal tract irritation, DO NOT induce emesis.
PREHOSPITAL ACTIVATED CHARCOAL ADMINISTRATION

Consider prehospital administration of activated charcoal as an aqueous slurry in patients with a potentially toxic ingestion who are awake and able to protect their airway. Activated charcoal is most effective when administered within one hour of ingestion. Administration in the prehospital setting has the potential to significantly decrease the time from toxin ingestion to activated charcoal administration, although it has not been shown to affect outcome (Alaspaa et al, 2005; Thakore & Murphy, 2002; Spiller & Rogers, 2002).

In patients who are at risk for the abrupt onset of seizures or mental status depression, activated charcoal should not be administered in the prehospital setting, due to the risk of aspiration in the event of spontaneous emesis.
The addition of flavoring agents (cola drinks, chocolate milk, cherry syrup) to activated charcoal improves the palatability for children and may facilitate successful administration (Guenther Skokan et al, 2001; Dagnone et al, 2002).

ACTIVATED CHARCOAL: Administer charcoal as a slurry (240 mL water/30 g charcoal). Usual dose: 25 to 100 g in adults/adolescents, 25 to 50 g in children (1 to 12 years), and 1 g/kg in infants less than 1 year old.

-RANGE OF TOXICITY

MINIMUM LETHAL EXPOSURE

GENERAL/SUMMARY

The minimum lethal human dose to this agent has not been delineated.

ANIMAL DATA

Applications of 4 to 8 mg of powered acid green to the conjunctival sac or 0.02 molar solution to the surface of the eye were not damaging to the eye in rabbits (HSDB , 2002).
Four-week old Osborne-Mendel rats were given weekly subcutaneous injections of approximately 15 mg C.I. acid green 3 for life. Of the 18 rats receiving the injection, 14 were still alive at 18 months, and 6 survived for 2 years. Four of the animals developed injection-site fibrosarcomas (IARC, 1978).
Forty four-week old Wistar rats had continual skin/fur contact with C.I. acid green 3 for 100 weeks. There was a stastically significant incidence of benign mammary tumors in the test group as compared with the controls (IARC, 1978).

CARCINOGENICITY

C.I. Acid Green 3 has been associated with experimental reproductive effects and reported mutation data, though its status as a carcinogen is questionable (Lewis, 2000; RTECS , 2002).
There is limited evidence of C.I. Acid Green 3's carcinogenicity in animals. It is not classifiable as to its carcinogenicity in humans (Group 3) (IARC, 1978).
ANIMAL STUDIES -

Four groups of Wistar rats, 4 to 6 weeks old, were fed 0.03 to 3 percent C.I. acid green 3 in their diets for 75 weeks. Histological examination of approximately half of the surviving rats showed malignant tumors (kidney carcinoma, liposarcoma and squamous cell carcinomas of the skin) in four of the rats. Benign skin lesions were also observed in two of the rats fed the highest dose (HSDB , 2002).

MAXIMUM TOLERATED EXPOSURE

GENERAL/SUMMARY

The maximum tolerated human exposure to this agent has not been delineated.
Those employed in trades involving exposure to paraphenylenediamine derivatives in dyes frequently become sensitized to azo dyes (HSDB , 2002).

Carcinogenicity Ratings for CAS4680-78-8 :

ACGIH (American Conference of Governmental Industrial Hygienists, 2010): Not Listed
EPA (U.S. Environmental Protection Agency, 2011): Not Listed
IARC (International Agency for Research on Cancer (IARC), 2016; International Agency for Research on Cancer, 2015; IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, 2010; IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, 2010a; IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, 2008; IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, 2007; IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, 2006; IARC, 2004): 3 ; Listed as: Guinea Green B

3 : The agent (mixture or exposure circumstance) is not classifiable as to its carcinogenicity to humans. This category is used most commonly for agents, mixtures and exposure circumstances for which the evidence of carcinogenicity is inadequate in humans and inadequate or limited in experimental animals. Exceptionally, agents (mixtures) for which the evidence of carcinogenicity is inadequate in humans but sufficient in experimental animals may be placed in this category when there is strong evidence that the mechanism of carcinogenicity in experimental animals does not operate in humans. Agents, mixtures and exposure circumstances that do not fall into any other group are also placed in this category.

NIOSH (National Institute for Occupational Safety and Health, 2007): Not Listed
MAK (DFG, 2002): Not Listed
NTP (U.S. Department of Health and Human Services, Public Health Service, National Toxicology Project ): Not Listed

TOXICITY AND RISK ASSESSMENT VALUES

EPA IRIS

EPA Risk Assessment Values for CAS4680-78-8 (U.S. Environmental Protection Agency, 2011):

Not Listed

TOXICITY VALUES

References: Budavari, 2000 IARC, 1978 Lewis, 2000 RTECS, 2002
- LD- (ORAL)RAT:
- LD50- (ORAL)RAT:
- TCLo- (INHALATION)RAT:
- TDLo- (ORAL)RAT:

-STANDARDS AND LABELS

WORKPLACE STANDARDS

ACGIH TLV Values for CAS4680-78-8 (American Conference of Governmental Industrial Hygienists, 2010):

Not Listed

AIHA WEEL Values for CAS4680-78-8 (AIHA, 2006):

Not Listed

NIOSH REL and IDLH Values for CAS4680-78-8 (National Institute for Occupational Safety and Health, 2007):

Not Listed

OSHA PEL Values for CAS4680-78-8 (U.S. Occupational Safety, and Health Administration (OSHA), 2010):

Not Listed

OSHA List of Highly Hazardous Chemicals, Toxics, and Reactives for CAS4680-78-8 (U.S. Occupational Safety and Health Administration, 2010):

Not Listed

ENVIRONMENTAL STANDARDS

EPA CERCLA, Hazardous Substances and Reportable Quantities for CAS4680-78-8 (U.S. Environmental Protection Agency, 2010):

Not Listed

EPA CERCLA, Hazardous Substances and Reportable Quantities, Radionuclides for CAS4680-78-8 (U.S. Environmental Protection Agency, 2010):

Not Listed

EPA RCRA Hazardous Waste Number for CAS4680-78-8 (U.S. Environmental Protection Agency, 2010b):

Not Listed
Editor's Note: The D, F, and K series waste numbers and Appendix VIII to Part 261 -- Hazardous Constituents were not included. Please refer to 40 CFR Part 261.

EPA SARA Title III, Extremely Hazardous Substance List for CAS4680-78-8 (U.S. Environmental Protection Agency, 2010):

Not Listed

EPA SARA Title III, Community Right-to-Know for CAS4680-78-8 (40 CFR 372.65, 2006; 40 CFR 372.28, 2006):

Listed as: C.I. Acid Green 3
Effective Date for Reporting Under 40 CFR 372.30: 1/1/87
Lower Thresholds for Chemicals of Special Concern under 40 CFR 372.28:

DOT List of Marine Pollutants for CAS4680-78-8 (49 CFR 172.101 - App. B, 2005):

Not Listed

EPA TSCA Inventory for CAS4680-78-8 (EPA, 2005):

Listed as: Benzenemethanaminium, N-ethyl-N-[4-[[4-[ethyl[(3-sulfophenyl)methyl]amino]phenyl]phenylmethylene]-2,5-cyclohexadien-1-ylidene]-3-sulfo-, inner salt, sodium salt

SHIPPING REGULATIONS

SURFACE

DOT -- Table of Hazardous Materials and Special Provisions (49 CFR 172.101, 2005):

Not Listed

ICAO International Shipping Name (ICAO, 2002):

Not Listed

LABELS

NFPA

NFPA Hazard Ratings for CAS4680-78-8 (NFPA, 2002):

Not Listed

-HANDLING AND STORAGE

HANDLING

Most water-soluble organic azo dyes are potential skin sensitiziers. Dermal contact to the dyes may cause allergic eczematous contact dermatitis, and color developing solutions has caused by lichen planus-like eruptions (HSDB , 2002).

-PERSONAL PROTECTION

SUMMARY

RECOMMENDED PROTECTIVE CLOTHING - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 171 (ERG, 2004)

Wear positive pressure self-contained breathing apparatus (SCBA).
Structural firefighters' protective clothing will only provide limited protection.

RESPIRATORY PROTECTION

Refer to "Recommendations for respirator selection" in the NIOSH Pocket Guide to Chemical Hazards on TOMES Plus(R) for respirator information.

PROTECTIVE CLOTHING

CHEMICAL PROTECTIVE CLOTHING. Search results for CAS 4680-78-8.

Specific recommendations and test data for this chemical were not found in the available manufacturers' product literature. A complete list of consulted manufacturers and references is presented below.

-PHYSICAL HAZARDS

FIRE HAZARD

SUMMARY

Editor's Note: This material is not listed in the Emergency Response Guidebook. Based on the material's physical and chemical properties, toxicity, or chemical group, a guide has been assigned. For additional technical information, contact one of the emergency response telephone numbers listed under Public Safety Measures.
POTENTIAL FIRE OR EXPLOSION HAZARDS - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 171 (ERG, 2004)
- Some may burn but none ignite readily.
- Containers may explode when heated.
- Some may be transported hot.

FLAMMABILITY CLASSIFICATION

NFPA Flammability Rating for CAS4680-78-8 (NFPA, 2002):

Not Listed

FIRE CONTROL/EXTINGUISHING AGENTS

SMALL FIRE PRECAUTIONS - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 171 (ERG, 2004)

Dry chemical, CO2, water spray or regular foam.

LARGE FIRE PRECAUTIONS - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 171 (ERG, 2004)

Water spray, fog or regular foam.
Move containers from fire area if you can do it without risk.
Do not scatter spilled material with high pressure water streams.
Dike fire-control water for later disposal.

TANK FIRE PRECAUTIONS - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 171 (ERG, 2004)

Cool containers with flooding quantities of water until well after fire is out.
Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.
ALWAYS stay away from tanks engulfed in fire.

NFPA Extinguishing Methods for CAS4680-78-8 (NFPA, 2002):

Not Listed

COMBUSTION TOXICITY

When heated to decomposition, C.I. Acid Green 3 emits very toxic fumes of nitrogen oxides, sulfur oxides and sodium monoxide (Lewis, 2000).

REACTIVITY HAZARD

No information found at the time of this review.

EVACUATION PROCEDURES

SUMMARY

Editor's Note: This material is not listed in the Table of Initial Isolation and Protective Action Distances.

SPILL - PUBLIC SAFETY EVACUATION DISTANCES - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 171(ERG, 2004)

Increase, in the downwind direction, as necessary, the isolation distance of at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids in all directions.

FIRE - PUBLIC SAFETY EVACUATION DISTANCES - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 171 (ERG, 2004)

If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

PUBLIC SAFETY MEASURES - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 171 (ERG, 2004)

CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number:

MEXICO:

SETIQ:

01-800-00-214-00 in the Mexican Republic;
For calls originating in Mexico City and the Metropolitan Area: 5559-1588;
For calls originating elsewhere, call: 011-52-555-559-1588.

CENACOM:

01-800-00-413-00 in the Mexican Republic;
For calls originating in Mexico City and the Metropolitan Area: 5550-1496, 5550-1552, 5550-1485, or 5550-4885;
For calls originating elsewhere, call: 011-52-555-550-1496, or 011-52-555-550-1552; 011-52-555-550-1485, or 011-52-555-550-4885.

ARGENTINA:

CIQUIME:

0-800-222-2933 in the Republic of Argentina;
For calls originating elsewhere, call: +54-11-4613-1100.

BRAZIL:

PRÓ-QUÍMICA:

0-800-118270 (Toll-free in Brazil);
For calls originating elsewhere, call: +55-11-232-1144 (Collect calls are accepted).

COLUMBIA:

CISPROQUIM:

01-800-091-6012 in Colombia;
For calls originating in Bogotá, Colombia, call: 288-6012;
For calls originating elsewhere, call: 011-57-1-288-6012.

CANADA:

CANUTEC:

613-996-6666 (Collect calls are accepted);
*666 cellular (in Canada only).

UNITED STATES:

CHEMTREC®:

1-800-424-9300 (Toll-free in the U.S., Canada, and the U.S. Virgin Islands);
703-527-3887 for calls originating elsewhere (Collect calls are accepted).

CHEM-TEL, INC.:

1-800-255-3924 (Toll-free in the U.S., Canada, and the U.S. Virgin Islands);
813-248-0585 for calls originating elsewhere (Collect calls are accepted).

INFOTRAC:

1-800-535-5053 (Toll-free in the U.S., Canada, and the U.S. Virgin Islands);
352-323-3500 for calls originating elsewhere (Collect calls are accepted).

3E COMPANY:

1-800-451-8346 (Toll-free in the U.S., Canada, and the U.S. Virgin Islands);
760-602-8703 for calls originating elsewhere (Collect calls are accepted).

NATIONAL RESPONSE CENTER (NRC):

1-800-424-8802 - (24 hours) (Toll-free in the U.S., Canada, and the U.S. Virgin Islands);
202-267-2675 for calls in the District of Columbia.

MILITARY SHIPMENTS:

703-697-0218 - Explosives/ammunition incidents (Collect calls are accepted);
1-800-851-8061 - All other dangerous goods incidents.

NATIONWIDE POISON CONTROL CENTER (United States only):

1-800-222-1222 (Toll-free in the U.S.).

For additional details see the section entitled "WHO TO CALL FOR ASSISTANCE" under the ERG Instructions.
As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.
Keep unauthorized personnel away.
Stay upwind.

AIHA ERPG Values for CAS4680-78-8 (AIHA, 2006):

Not Listed

DOE TEEL Values for CAS4680-78-8 (U.S. Department of Energy, Office of Emergency Management, 2010):

Not Listed

AEGL Values for CAS4680-78-8 (National Research Council, 2010; National Research Council, 2009; National Research Council, 2008; National Research Council, 2007; NRC, 2001; NRC, 2002; NRC, 2003; NRC, 2004; NRC, 2004; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; United States Environmental Protection Agency Office of Pollution Prevention and Toxics, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; 62 FR 58840, 1997; 65 FR 14186, 2000; 65 FR 39264, 2000; 65 FR 77866, 2000; 66 FR 21940, 2001; 67 FR 7164, 2002; 68 FR 42710, 2003; 69 FR 54144, 2004):

Not Listed

NIOSH IDLH Values for CAS4680-78-8 (National Institute for Occupational Safety and Health, 2007):

Not Listed

CONTAINMENT/WASTE TREATMENT OPTIONS

SUMMARY

SPILL OR LEAK PRECAUTIONS - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 171 (ERG, 2004)
- Do not touch or walk through spilled material.
- Stop leak if you can do it without risk.
- Prevent dust cloud.
- Avoid inhalation of asbestos dust.
RECOMMENDED PROTECTIVE CLOTHING - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 171 (ERG, 2004)
- Wear positive pressure self-contained breathing apparatus (SCBA).
- Structural firefighters' protective clothing will only provide limited protection.

SMALL LEAK/SPILL

SMALL SPILL PRECAUTIONS - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 171 (ERG, 2004)
- Take up with sand or other non-combustible absorbent material and place into containers for later disposal.
SMALL DRY SPILL PRECAUTIONS - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 171 (ERG, 2004)
- With clean shovel place material into clean, dry container and cover loosely; move containers from spill area.

LARGE LEAK/SPILL

LARGE SPILL PRECAUTIONS - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 171 (ERG, 2004)
- Dike far ahead of liquid spill for later disposal.
- Cover powder spill with plastic sheet or tarp to minimize spreading.
- Prevent entry into waterways, sewers, basements or confined areas.

-ENVIRONMENTAL HAZARD MANAGEMENT

POLLUTION HAZARD

No information found at the time of this review.

ABIOTIC DEGRADATION

No information found at the time of this review.

ENVIRONMENTAL TOXICITY

No information found at the time of this review.

-PHYSICAL/CHEMICAL PROPERTIES

MOLECULAR WEIGHT

691.81

DESCRIPTION/PHYSICAL STATE

C.I. Acid Green 3 exists as a dull, dark green powder or a bright, crystalline solid (Budavari, 2000; IARC, 1978).

SOLUBILITY

IN WATER

Soluble (IARC, 1978)

IN ORGANIC SOLVENTS

C.I. Acid Green 3 is slightly soluble in ethanol (IARC, 1978).

OTHER

C.I. Acid Green 3 is sparingly soluble in alcohol (Budavari, 2000).
It dissolves in concentrated sulfuric acid (Budavari, 2000).

-REFERENCES

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Information to evaluate chemical incidents

Information to evaluate chemical incidents

Information to evaluate chemical incidents