BUTOXYETHOXY ETHANOL
HAZARDTEXT ®
Information to help in the initial response for evaluating chemical incidents
 -IDENTIFICATION
SYNONYMS
Diethylene glycol monobutyl ether Diglycol monobutyl ether 2-(2-butoxyethoxy ethanol) Butoxydiethylene glycol Butyl carbitol Butyl digol DGBE (diethylene glycol butyl ether) BUCB BUTYL DIOXITOL ETHANOL, BUTOXYETHOXY
IDENTIFIERS
USES/FORMS/SOURCES
It is primarily used as a solvent in hard-surface cleaners and inks, and as a solvent and coalescing agent in paints and other coatings (Clayton & Clayton, 1994), as well as a melting-out solution in the textile industry or as a solvent for cellulose nitrate.
-CLINICAL EFFECTS
GENERAL CLINICAL EFFECTS
- USES: Butoxyethoxy ethanol or diethylene glycol monobutyl ether (DGBE) is a colorless, odorless liquid. It is primarily used as a solvent in hard-surface cleaners and inks, and as a solvent and coalescing agent in paints and other coatings. It is also used as a melting-out solution in the textile industry or as a solvent for cellulose nitrate.
- TOXICOLOGY: DGBE has a low order of toxicity via the oral, dermal and inhalational route. The primary urinary metabolites are 2-butoxyethoxyacetic acid, along with diethylene glycol, and hydroxybutoxyethoxyacetic acid.
- EPIDEMIOLOGY: Acute poisoning is relatively rare but DGBE is used widely in industrial settings and chronic exposure may occur in many workers among certain industries.
MILD TO MODERATE TOXICITY: DGBE is an irritant to eyes, skin, and mucosa. Increased intraocular pressure was noted after instillation of a 0.4 mL of a 10% solution of DGBE. Patients may experience nausea, vomiting, and diarrhea following ingestion of DGBE. SEVERE TOXICITY: Tachypnea, cyanosis, uremia and impaired kidney function have been observed. Large and intentional exposures to other diglycol ethers have resulted in reports of CNS depression, metabolic acidosis, renal injury, and acute lung injury. Theoretically, acidosis may occur.
- Editor's Note: An ERG guide with information appropriate to this material does not exist.
-FIRST AID
FIRST AID AND PREHOSPITAL TREATMENT
- Gastrointestinal decontamination is not recommended after ingestion because of the risk of CNS and respiratory depression and aspiration. Remove contaminated clothing and wash exposed area thoroughly with soap and water. Irrigate exposed eyes with copious amounts of room temperature water for at least 15 minutes. If present, carefully remove contact lenses.
-RANGE OF TOXICITY
MAXIMUM TOLERATED EXPOSURE
- SUMMARY: DGBE has a low order of toxicity via the oral, dermal or inhalational route (Clayton & Clayton, 1994). The dermal route is the most likely source for exposure, but is generally only toxic following prolonged contact in large quantities (HSDB , 2000).
- There has been only one human case reported. Two milliliters per kilogram of an unknown concentration resulted in cyanosis, tachypnea, and slight uremia (Brennaas, 1960).
- The ethers of diethylene glycol are lower in toxicity than the ethers of ethylene glycol, but they reportedly have similar characteristics (HSDB , 2000).
ORAL/NON-TOXIC: Rats consuming drinking water for 30 days containing 0.051 grams/kilogram/day developed no adverse effects (Smyth & Carpenter, 1948). ORAL/TOXIC: Rats consuming drinking water for 30 days containing 0.094 and 0.65 grams/kilogram/day developed reduction in appetite and histopathologic injury in either the kidney, liver, spleen, or testes (Smyth & Carpenter, 1948). INHALATION: Animal data indicate there is little hazard associated with a single vapor exposure in part because of its low vapor concentration (Clayton & Clayton, 1994).
- Carcinogenicity Ratings for CAS112-34-5 :
ACGIH (American Conference of Governmental Industrial Hygienists, 2010): Not Listed ; Listed as: Diethylene glycol monobutyl ether EPA (U.S. Environmental Protection Agency, 2011): Not Listed IARC (International Agency for Research on Cancer (IARC), 2016; International Agency for Research on Cancer, 2015; IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, 2010; IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, 2010a; IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, 2008; IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, 2007; IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, 2006; IARC, 2004): Not Listed NIOSH (National Institute for Occupational Safety and Health, 2007): Not Listed MAK (DFG, 2002): Not Listed NTP (U.S. Department of Health and Human Services, Public Health Service, National Toxicology Project ): Not Listed
TOXICITY AND RISK ASSESSMENT VALUES
- EPA Risk Assessment Values for CAS112-34-5 (U.S. Environmental Protection Agency, 2011):
-STANDARDS AND LABELS
WORKPLACE STANDARDS
- ACGIH TLV Values for CAS112-34-5 (American Conference of Governmental Industrial Hygienists, 2010):
Editor's Note: The listed values are recommendations or guidelines developed by ACGIH(R) to assist in the control of health hazards. They should only be used, interpreted and applied by individuals trained in industrial hygiene. Before applying these values, it is imperative to read the introduction to each section in the current TLVs(R) and BEI(R) Book and become familiar with the constraints and limitations to their use. Always consult the Documentation of the TLVs(R) and BEIs(R) before applying these recommendations and guidelines.
- AIHA WEEL Values for CAS112-34-5 (AIHA, 2006):
- NIOSH REL and IDLH Values for CAS112-34-5 (National Institute for Occupational Safety and Health, 2007):
- OSHA PEL Values for CAS112-34-5 (U.S. Occupational Safety, and Health Administration (OSHA), 2010):
- OSHA List of Highly Hazardous Chemicals, Toxics, and Reactives for CAS112-34-5 (U.S. Occupational Safety and Health Administration, 2010):
ENVIRONMENTAL STANDARDS
- EPA CERCLA, Hazardous Substances and Reportable Quantities for CAS112-34-5 (U.S. Environmental Protection Agency, 2010):
- EPA CERCLA, Hazardous Substances and Reportable Quantities, Radionuclides for CAS112-34-5 (U.S. Environmental Protection Agency, 2010):
- EPA RCRA Hazardous Waste Number for CAS112-34-5 (U.S. Environmental Protection Agency, 2010b):
- EPA SARA Title III, Extremely Hazardous Substance List for CAS112-34-5 (U.S. Environmental Protection Agency, 2010):
- EPA SARA Title III, Community Right-to-Know for CAS112-34-5 (40 CFR 372.65, 2006; 40 CFR 372.28, 2006):
- DOT List of Marine Pollutants for CAS112-34-5 (49 CFR 172.101 - App. B, 2005):
- EPA TSCA Inventory for CAS112-34-5 (EPA, 2005):
LABELS
- NFPA Hazard Ratings for CAS112-34-5 (NFPA, 2002):
-PERSONAL PROTECTION
SUMMARY
- Editor's Note: An ERG guide with information appropriate to this material does not exist.
PROTECTIVE CLOTHING
- CHEMICAL PROTECTIVE CLOTHING. Search results for CAS 112-34-5.
-PHYSICAL HAZARDS
FIRE HAZARD
- FLAMMABILITY CLASSIFICATION
- NFPA Flammability Rating for CAS112-34-5 (NFPA, 2002):
- FIRE CONTROL/EXTINGUISHING AGENTS
- Editor's Note: An ERG guide with information appropriate to this material does not exist.
- NFPA Extinguishing Methods for CAS112-34-5 (NFPA, 2002):
EVACUATION PROCEDURES
- Editor's Note: An ERG guide with information appropriate to this material does not exist.
- AIHA ERPG Values for CAS112-34-5 (AIHA, 2006):
- DOE TEEL Values for CAS112-34-5 (U.S. Department of Energy, Office of Emergency Management, 2010):
Listed as Butoxyethoxy)-ethanol, 2-(2- (Diethylene glycol monobutyl ether) TEEL-0 (units = ppm): 10 TEEL-1 (units = ppm): 15 TEEL-2 (units = ppm): 100 TEEL-3 (units = ppm): 350 Definitions: TEEL-0: The threshold concentration below which most people will experience no adverse health effects. TEEL-1: The airborne concentration (expressed as ppm [parts per million] or mg/m(3) [milligrams per cubic meter]) of a substance above which it is predicted that the general population, including susceptible individuals, could experience notable discomfort, irritation, or certain asymptomatic, nonsensory effects. However, these effects are not disabling and are transient and reversible upon cessation of exposure. TEEL-2: The airborne concentration (expressed as ppm or mg/m(3)) of a substance above which it is predicted that the general population, including susceptible individuals, could experience irreversible or other serious, long-lasting, adverse health effects or an impaired ability to escape. TEEL-3: The airborne concentration (expressed as ppm or mg/m(3)) of a substance above which it is predicted that the general population, including susceptible individuals, could experience life-threatening adverse health effects or death.
- AEGL Values for CAS112-34-5 (National Research Council, 2010; National Research Council, 2009; National Research Council, 2008; National Research Council, 2007; NRC, 2001; NRC, 2002; NRC, 2003; NRC, 2004; NRC, 2004; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; 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62 FR 58840, 1997; 65 FR 14186, 2000; 65 FR 39264, 2000; 65 FR 77866, 2000; 66 FR 21940, 2001; 67 FR 7164, 2002; 68 FR 42710, 2003; 69 FR 54144, 2004):
- NIOSH IDLH Values for CAS112-34-5 (National Institute for Occupational Safety and Health, 2007):
CONTAINMENT/WASTE TREATMENT OPTIONS
-PHYSICAL/CHEMICAL PROPERTIES
MOLECULAR WEIGHT
DESCRIPTION/PHYSICAL STATE
- a colorless, odorless liquid (Budavari, 1996)
VAPOR PRESSURE
- 0.02 mmHg (at 20 degrees C) (HSDB , 1990)
SPECIFIC GRAVITY
- OTHER TEMPERATURE AND/OR PRESSURE
FREEZING/MELTING POINT
BOILING POINT
- 230.4 degrees C (Budavari, 1989)
FLASH POINT
- 110 degrees C (Budavari, 1989)
AUTOIGNITION TEMPERATURE
- 442 degrees F (HSDB , 1990)
SOLUBILITY
oils: miscible (Budavari, 1989) benzene: soluble (HSDB , 1990) ether: very soluble (HSDB , 1990) alcohol: very soluble (HSDB , 1990) acetone: very soluble (HSDB , 1990)
OTHER/PHYSICAL
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