BERYLLIUM NITRATE

Beryllium nitrate is an acidic salt and is very irritating. Acute beryllium poisoning consists of irritation of conjunctivae, skin ulcerations, nose bleeds and nasal discharge, headache, fatigue, fever, and chest pain. Acute beryllium pneumonitis may result from both high and low exposures; recovery may occur within one to six months. Right heart failure, due to increased pulmonary arterial resistance, occurs with acute exposures.

This compound will be directly irritating to the skin, eyelids, and mucous membranes. Contact dermatitis may develop. Acute pulmonary lesions have been produced after a few minutes exposure to beryllium fluoride, a related compound. Decreased pulmonary function can occur with acute exposures. This compound possesses a very low ingestion toxicity.

Chronic beryllium disease is an idiosyncratic disorder; only about 1 to 20 of the most heavily exposed workers is affected. Diagnosis requires history of exposure, compatible histologic findings, and quantitative tissue analysis.

Symptoms of chronic disease begin with coughing, shortness of breath, loss of appetite, loss of weight, and fatigue. Cyanosis is common; the pulse and respiratory rates are elevated. Red blood cell count may be elevated. Clinical improvement years may occur during several years following removal from the exposure. No treatment is available for berylliosis.

Studies of beryllium workers have found increased rates of granulomatous hepatitis, and reduced pulmonary function due to the fibrosis caused by berylliosis.

SENSITIZER - Beryllium was a sensitizer in a footpad reaction and macrophage migration tests on mice.

Lung cancers have been observed in workers who developed acute chemical workers or bronchitis secondary to beryllium exposure. Beryllium is classified as Group 1 (carcinogenic to humans) by IARC.

Beryllium was embryotoxic and teratogenic by exerting toxic effects on the mother and fetus.

POTENTIAL HEALTH HAZARDS - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 141 (ERG, 2004)

Toxic by ingestion.
Inhalation of dust is toxic.
Fire may produce irritating, corrosive and/or toxic gases.
Contact with substance may cause severe burns to skin and eyes.
Runoff from fire control or dilution water may cause pollution.

-MEDICAL TREATMENT

LIFE SUPPORT

Support respiratory and cardiovascular function.

SUMMARY

FIRST AID - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 141 (ERG, 2004)

Move victim to fresh air.
Call 911 or emergency medical service.
Give artificial respiration if victim is not breathing.
Administer oxygen if breathing is difficult.
Remove and isolate contaminated clothing and shoes.
Contaminated clothing may be a fire risk when dry.
In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes.
Keep victim warm and quiet.
Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves.

FIRST AID

INHALATION EXPOSURE -

INHALATION: Move patient to fresh air. Monitor for respiratory distress. If cough or difficulty breathing develops, evaluate for respiratory tract irritation, bronchitis, or pneumonitis. Administer oxygen and assist ventilation as required. Treat bronchospasm with an inhaled beta2-adrenergic agonist. Consider systemic corticosteroids in patients with significant bronchospasm.
Immediately hospitalize in acute exposure cases and observe for 72 hours for onset of pneumonitis (HSDB , 1992).
Bed rest and symptomatic treatment may be all that is required in mild forms of beryllium poisoning.
Corticosteroids may be a useful adjunct for controlling dyspnea and delaying the onset of right heart failure and pulmonary insufficiency after chronic exposure.

EYE EXPOSURE -

DECONTAMINATION: Remove contact lenses and irrigate exposed eyes with copious amounts of room temperature 0.9% saline or water for at least 15 minutes. If irritation, pain, swelling, lacrimation, or photophobia persist after 15 minutes of irrigation, the patient should be seen in a healthcare facility.

DERMAL EXPOSURE -

DECONTAMINATION: Remove contaminated clothing and jewelry and place them in plastic bags. Wash exposed areas with soap and water for 10 to 15 minutes with gentle sponging to avoid skin breakdown. A physician may need to examine the area if irritation or pain persists (Burgess et al, 1999).
If beryllium enters through cut or puncture wounds, a physician immediately should cleanse the area thoroughly and excise any imbedded beryllium material (HSDB , 1992).
Thoroughly cleanse any skin that may have embedded beryllium.
Contaminated clothing should be removed and isolated so that no direct personal exposure occurs during handling and cleaning (HSDB , 1992).

ORAL EXPOSURE -

DILUTION: If no respiratory compromise is present, administer milk or water as soon as possible after ingestion. Dilution may only be helpful if performed in the first seconds to minutes after ingestion. The ideal amount is unknown; no more than 8 ounces (240 mL) in adults and 4 ounces (120 mL) in children is recommended to minimize the risk of vomiting.
Material may be irritating or caustic depending on concentration. Emesis should be used with caution if at all.

-RANGE OF TOXICITY

MINIMUM LETHAL EXPOSURE

GENERAL/SUMMARY

The minimum lethal human dose to this agent has not been delineated.

MAXIMUM TOLERATED EXPOSURE

GENERAL/SUMMARY

The maximum tolerated human exposure to this agent has not been delineated.

Carcinogenicity Ratings for CAS13597-99-4 :

ACGIH (American Conference of Governmental Industrial Hygienists, 2010): Not Listed
EPA (U.S. Environmental Protection Agency, 2011): Not Listed
IARC (International Agency for Research on Cancer (IARC), 2016; International Agency for Research on Cancer, 2015; IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, 2010; IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, 2010a; IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, 2008; IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, 2007; IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, 2006; IARC, 2004): 1 ; Listed as: Beryllium nitrate

1 : The agent (mixture) is carcinogenic to humans. The exposure circumstance entails exposures that are carcinogenic to humans. This category is used when there is sufficient evidence of carcinogenicity in humans. Exceptionally, an agent (mixture) may be placed in this category when evidence of carcinogenicity in humans is less than sufficient but there is sufficient evidence of carcinogenicity in experimental animals and strong evidence in exposed humans that the agent (mixture) acts through a relevant mechanism of carcinogenicity.

NIOSH (National Institute for Occupational Safety and Health, 2007): Not Listed
MAK (DFG, 2002): Not Listed
NTP (U.S. Department of Health and Human Services, Public Health Service, National Toxicology Project ): Not Listed

TOXICITY AND RISK ASSESSMENT VALUES

EPA IRIS

EPA Risk Assessment Values for CAS13597-99-4 (U.S. Environmental Protection Agency, 2011):

Not Listed

TOXICITY VALUES

References: RTECS, 1992 Sax & Lewis, 1989
- LD50- (INTRAPERITONEAL)MOUSE:
- LD50- (INTRAVENOUS)MOUSE:
- LDLo- (INTRAPERITONEAL)GUINEA_PIG:
- LDLo- (SUBCUTANEOUS)MOUSE:
- TDLo- (INTRATRACHEAL)RAT:

-STANDARDS AND LABELS

WORKPLACE STANDARDS

ACGIH TLV Values for CAS13597-99-4 (American Conference of Governmental Industrial Hygienists, 2010):

Not Listed

AIHA WEEL Values for CAS13597-99-4 (AIHA, 2006):

Not Listed

NIOSH REL and IDLH Values for CAS13597-99-4 (National Institute for Occupational Safety and Health, 2007):

Not Listed

OSHA PEL Values for CAS13597-99-4 (U.S. Occupational Safety, and Health Administration (OSHA), 2010):

Not Listed

OSHA List of Highly Hazardous Chemicals, Toxics, and Reactives for CAS13597-99-4 (U.S. Occupational Safety and Health Administration, 2010):

Not Listed

ENVIRONMENTAL STANDARDS

EPA CERCLA, Hazardous Substances and Reportable Quantities for CAS13597-99-4 (U.S. Environmental Protection Agency, 2010):

Listed as: Beryllium nitrate
Final Reportable Quantity, in pounds (kilograms):

1 (0.454)

Additional Information:

EPA CERCLA, Hazardous Substances and Reportable Quantities, Radionuclides for CAS13597-99-4 (U.S. Environmental Protection Agency, 2010):

Not Listed

EPA RCRA Hazardous Waste Number for CAS13597-99-4 (U.S. Environmental Protection Agency, 2010b):

Not Listed
Editor's Note: The D, F, and K series waste numbers and Appendix VIII to Part 261 -- Hazardous Constituents were not included. Please refer to 40 CFR Part 261.

EPA SARA Title III, Extremely Hazardous Substance List for CAS13597-99-4 (U.S. Environmental Protection Agency, 2010):

Not Listed

EPA SARA Title III, Community Right-to-Know for CAS13597-99-4 (40 CFR 372.65, 2006; 40 CFR 372.28, 2006):

Not Listed

DOT List of Marine Pollutants for CAS13597-99-4 (49 CFR 172.101 - App. B, 2005):

Not Listed

EPA TSCA Inventory for CAS13597-99-4 (EPA, 2005):

Listed as: Nitric acid, beryllium salt

SHIPPING REGULATIONS

SURFACE

DOT -- Table of Hazardous Materials and Special Provisions for UN/NA Number 2464 (49 CFR 172.101, 2005):

Hazardous materials descriptions and proper shipping name: Beryllium nitrate

Symbol(s): Not Listed
Hazard class or Division: 5.1

5.1: Oxidizer. See 49 CFR section 173.127 for definitions.

Identification Number: UN2464
Packing Group: II

II: Packing Group II - indicates the degree of danger presented by the material is medium.

Label(s) required (if not excepted): 5.1, 6.1

5.1: Oxidizer.
6.1: Poison Inhalation Hazard (inhalation hazard, Zone A or B) or Poison (other than inhalation hazard, Zone A or B; the packing group for a material is indicated in column 5 of the table.).

Special Provisions: IB8, IP2, IP4, T3, TP33

IB8: Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1 and 31HZ2); Fiberboard (11G); Wooden (11C, 11D and 11F); Flexible (13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 or 13M2).
IP2: When IBCs other than metal or rigid plastics IBCs are used, they must be offered for transportation in a closed freight container or a closed transport vehicle.
IP4: Flexible, fiberboard or wooden IBCs must be sift-proof and water-resistant or be fitted with a sift-proof and water-resistant liner.
T3: Minimum test pressure (bar): 2.65; Minimum shell thickness (in mm-reference steel) (See sxn.178.274(d)): sxn.178.274(d)(2); Pressure-relief requirements (See sxn.178.275(g)): Normal; Bottom opening requirements (See sxn.178.275(d)): sxn.178.275(d)(2).
TP33: The portable tank instruction assigned for this substance applies for granular and powdered solids and for solids which are filled and discharged at temperatures above their melting point which are cooled and transported as a solid mass. Solid substances transported or offered for transport above their melting point are authorized for transportation in portable tanks conforming to the provisions of portable tank instruction T4 for solid substances of packing group III or T7 for solid substances of packing group II, unless a tank with more stringent requirements for minimum shell thickness, maximum allowable working pressure, pressure-relief devices or bottom outlets are assigned in which case the more stringent tank instruction and special provisions shall apply. Filling limits must be in accordance with portable tank special provision TP3. Solids meeting the defnintion of an elevated temperature material must be transported in accordance with the applicable requirements of this subchapter.

Packaging Authorizations (refer to 49 CFR 173.***):

Exceptions: 152
Non-bulk packaging: 212
Bulk packaging: 242

Quantity Limitations:

Passenger aircraft or railcar: 5 kg
Cargo aircraft only: 25 kg

Vessel Stowage Requirements:

Vessel stowage location: A

A: The material may be stowed "on deck" or "under deck" on a cargo vessel and on a passenger vessel.

Vessel stowage other: Not Listed

ICAO International Shipping Name for UN2464 (ICAO, 2002):

Proper Shipping Name: Beryllium nitrate
UN Number: 2464

LABELS

NFPA

NFPA Hazard Ratings for CAS13597-99-4 (NFPA, 2002):

Not Listed

-HANDLING AND STORAGE

STORAGE

CONTAINER

Keep beryllium nitrate stored in dry, tightly closed containers, in a cool place (Budavari, 1989; OHM/TADS , 1992).
Protect containers from physical damage (HSDB , 1992).

ROOM/CABINET RECOMMENDATIONS

Storage temperature: Ambient (CHRIS , 1992)

INCOMPATIBILITIES

Store away from combustibles (wood, paper, oil) acids, caustics chlorinated hydrocarbons, and oxidizing materials (HSDB , 1992).

-PERSONAL PROTECTION

SUMMARY

RECOMMENDED PROTECTIVE CLOTHING - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 141 (ERG, 2004)

Wear positive pressure self-contained breathing apparatus (SCBA).
Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection.
Structural firefighters' protective clothing will only provide limited protection.

RESPIRATORY PROTECTION

Refer to "Recommendations for respirator selection" in the NIOSH Pocket Guide to Chemical Hazards on TOMES Plus(R) for respirator information.

PROTECTIVE CLOTHING

CHEMICAL PROTECTIVE CLOTHING. Search results for CAS 13597-99-4.

Specific recommendations and test data for this chemical were not found in the available manufacturers' product literature. A complete list of consulted manufacturers and references is presented below.

-PHYSICAL HAZARDS

FIRE HAZARD

SUMMARY

POTENTIAL FIRE OR EXPLOSION HAZARDS - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 141 (ERG, 2004)
- These substances will accelerate burning when involved in a fire.
- May explode from heat or contamination.
- Some may burn rapidly.
- Some will react explosively with hydrocarbons (fuels).
- May ignite combustibles (wood, paper, oil, clothing, etc.).
- Containers may explode when heated.
- Runoff may create fire or explosion hazard.
Beryllium is non-combustible. However, it decomposes at between 100 to 200 degrees C, burns rapidly, and may ignite other combustible materials, particularly fuels (AAR, 1987; (HSDB , 1992; Sax & Lewis, 1987).

FLAMMABILITY CLASSIFICATION

NFPA Flammability Rating for CAS13597-99-4 (NFPA, 2002):

Not Listed

FIRE CONTROL/EXTINGUISHING AGENTS

SMALL FIRE PRECAUTIONS - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 141 (ERG, 2004)

Use water. Do not use dry chemicals or foams. CO2 or Halon® may provide limited control.

LARGE FIRE PRECAUTIONS - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 141 (ERG, 2004)

Flood fire area with water from a distance.
Move containers from fire area if you can do it without risk.
Do not move cargo or vehicle if cargo has been exposed to heat.
Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.
Cool containers with flooding quantities of water until well after fire is out.
ALWAYS stay away from tanks engulfed in fire.
For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn.

NFPA Extinguishing Methods for CAS13597-99-4 (NFPA, 2002):

Not Listed

For small fires, control with dry chemical, carbon dioxide, Halon, or water spray. For large fires flood with water using water spray or fog (HSDB , 1992).

Cool all affected containers with flooding quantities of water applied from as far a distance as possible (AAR, 1987).
Combustibles increase the intensity of the fire (CHRIS , 1992).

COMBUSTION TOXICITY

Irritating and toxic gases, including beryllium oxides and oxides of nitrogen, may be produced during decomposition of beryllium nitrate in a fire (AAR, 1987; (CHRIS , 1992; HSDB , 1992).

EXPLOSION HAZARD

An explosion hazard is present if large quantities, especially as a fine dust, of beryllium nitrate are involved in fire. Also prolonged exposure to heat or fire may create an explosion (AAR, 1987).

Beryllium nitrate reacts violently with fuels (HSDB , 1992).

DUST/VAPOR HAZARD

Beryllium nitrate dust is extremely toxic; avoid both inhalation, skin, as well as mucous membrane contact (OHM/TADS , 1992).

Fire may suspend toxic dusts (OHM/TADS , 1992).

Beryllium nitrate dusts must be rigidly controlled to prevent exposure (HSDB , 1992).

Suppress suspension of dusts (OHM/TADS , 1992).

REACTIVITY HAZARD

Beryllium nitrate will form binary reactions with (OHM/TADS , 1992):

Cyanides
Esters
Phospham
Phosphorous
Sodium hypophosphite
Stannous chloride
Thiocyanates

In WATER strong acid solutions are formed (OHM/TADS , 1992).

In presence of moisture, it will form a weak solution of nitric acid (CHRIS , 1992).

Beryllium nitrate will corrode wood and most metals in moist atmospheres (HSDB , 1992).

Beryllium nitrate reacts violently with fuels (HSDB , 1992).

may react with combustibles (wood, paper, oil) acids, caustics, chlorinated hydrocarbons, and oxidizing materials (HSDB , 1992).

EVACUATION PROCEDURES

SUMMARY

Editor's Note: This material is not listed in the Table of Initial Isolation and Protective Action Distances.

LARGE SPILL - PUBLIC SAFETY EVACUATION DISTANCES - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 141 (ERG, 2004)

Consider initial downwind evacuation for at least 100 meters (330 feet).

FIRE - PUBLIC SAFETY EVACUATION DISTANCES - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 141 (ERG, 2004)

If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

PUBLIC SAFETY MEASURES - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 141 (ERG, 2004)

CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number:

MEXICO:

SETIQ:

01-800-00-214-00 in the Mexican Republic;
For calls originating in Mexico City and the Metropolitan Area: 5559-1588;
For calls originating elsewhere, call: 011-52-555-559-1588.

CENACOM:

01-800-00-413-00 in the Mexican Republic;
For calls originating in Mexico City and the Metropolitan Area: 5550-1496, 5550-1552, 5550-1485, or 5550-4885;
For calls originating elsewhere, call: 011-52-555-550-1496, or 011-52-555-550-1552; 011-52-555-550-1485, or 011-52-555-550-4885.

ARGENTINA:

CIQUIME:

0-800-222-2933 in the Republic of Argentina;
For calls originating elsewhere, call: +54-11-4613-1100.

BRAZIL:

PRÓ-QUÍMICA:

0-800-118270 (Toll-free in Brazil);
For calls originating elsewhere, call: +55-11-232-1144 (Collect calls are accepted).

COLUMBIA:

CISPROQUIM:

01-800-091-6012 in Colombia;
For calls originating in Bogotá, Colombia, call: 288-6012;
For calls originating elsewhere, call: 011-57-1-288-6012.

CANADA:

CANUTEC:

613-996-6666 (Collect calls are accepted);
*666 cellular (in Canada only).

UNITED STATES:

CHEMTREC®:

1-800-424-9300 (Toll-free in the U.S., Canada, and the U.S. Virgin Islands);
703-527-3887 for calls originating elsewhere (Collect calls are accepted).

CHEM-TEL, INC.:

1-800-255-3924 (Toll-free in the U.S., Canada, and the U.S. Virgin Islands);
813-248-0585 for calls originating elsewhere (Collect calls are accepted).

INFOTRAC:

1-800-535-5053 (Toll-free in the U.S., Canada, and the U.S. Virgin Islands);
352-323-3500 for calls originating elsewhere (Collect calls are accepted).

3E COMPANY:

1-800-451-8346 (Toll-free in the U.S., Canada, and the U.S. Virgin Islands);
760-602-8703 for calls originating elsewhere (Collect calls are accepted).

NATIONAL RESPONSE CENTER (NRC):

1-800-424-8802 - (24 hours) (Toll-free in the U.S., Canada, and the U.S. Virgin Islands);
202-267-2675 for calls in the District of Columbia.

MILITARY SHIPMENTS:

703-697-0218 - Explosives/ammunition incidents (Collect calls are accepted);
1-800-851-8061 - All other dangerous goods incidents.

NATIONWIDE POISON CONTROL CENTER (United States only):

1-800-222-1222 (Toll-free in the U.S.).

For additional details see the section entitled "WHO TO CALL FOR ASSISTANCE" under the ERG Instructions.
As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.
Keep unauthorized personnel away.
Stay upwind.
Keep out of low areas.
Ventilate closed spaces before entering.

Issue POISON warning and restrict access (CHRIS , 1992).

Beach/shore restoration: Restrict access to public until clean-up is completed (CHRIS , 1992; OHM/TADS , 1992).

AIHA ERPG Values for CAS13597-99-4 (AIHA, 2006):

Not Listed

DOE TEEL Values for CAS13597-99-4 (U.S. Department of Energy, Office of Emergency Management, 2010):

Listed as Beryllium nitrate
TEEL-0 (units = mg/m3): 0.00104
TEEL-1 (units = mg/m3): 1.5
TEEL-2 (units = mg/m3): 10.4
TEEL-3 (units = mg/m3): 83
Definitions:

TEEL-0: The threshold concentration below which most people will experience no adverse health effects.
TEEL-1: The airborne concentration (expressed as ppm [parts per million] or mg/m(3) [milligrams per cubic meter]) of a substance above which it is predicted that the general population, including susceptible individuals, could experience notable discomfort, irritation, or certain asymptomatic, nonsensory effects. However, these effects are not disabling and are transient and reversible upon cessation of exposure.
TEEL-2: The airborne concentration (expressed as ppm or mg/m(3)) of a substance above which it is predicted that the general population, including susceptible individuals, could experience irreversible or other serious, long-lasting, adverse health effects or an impaired ability to escape.
TEEL-3: The airborne concentration (expressed as ppm or mg/m(3)) of a substance above which it is predicted that the general population, including susceptible individuals, could experience life-threatening adverse health effects or death.

AEGL Values for CAS13597-99-4 (National Research Council, 2010; National Research Council, 2009; National Research Council, 2008; National Research Council, 2007; NRC, 2001; NRC, 2002; NRC, 2003; NRC, 2004; NRC, 2004; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; United States Environmental Protection Agency Office of Pollution Prevention and Toxics, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; 62 FR 58840, 1997; 65 FR 14186, 2000; 65 FR 39264, 2000; 65 FR 77866, 2000; 66 FR 21940, 2001; 67 FR 7164, 2002; 68 FR 42710, 2003; 69 FR 54144, 2004):

Not Listed

NIOSH IDLH Values for CAS13597-99-4 (National Institute for Occupational Safety and Health, 2007):

Not Listed

CONTAINMENT/WASTE TREATMENT OPTIONS

SUMMARY

SPILL OR LEAK PRECAUTIONS - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 141 (ERG, 2004)
- Keep combustibles (wood, paper, oil, etc.) away from spilled material.
- Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.
- Stop leak if you can do it without risk.
RECOMMENDED PROTECTIVE CLOTHING - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 141 (ERG, 2004)
- Wear positive pressure self-contained breathing apparatus (SCBA).
- Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection.
- Structural firefighters' protective clothing will only provide limited protection.
Shovel small, dry spills into clean, dry covered container and dispose according to environmental regulations. Contain large liquid spills (HSDB , 1992).
Solids: Cover solids with a plastic sheet to prevent dissolving in rain or fire-fighting water (AAR, 1987).
Water Spill/Liquids: Dam stream to reduce flow of beryllium nitrate. Build a dike far ahead to contain; and dig a pit, lagoon, or holding area to collect large leaks/spills (AAR, 1987; (HSDB , 1992; OHM/TADS , 1992).
Keep beryllium nitrate out of sewers and water sources (AAR, 1987).
May be dangerous if it enters water intakes; notify nearby water plant operators, health and wildlife officials (CHRIS , 1992).
Water Spill: Use mechanical dredges or lifts to remove immobilized masses of pollutants or precipitates (AAR, 1987).
Environmental regulatory agencies must be consulted before landfilling beryllium nitrate waste or sludge (HSDB , 1992).
Treatment: To dispose of small quantities, dissolve in 6M hydrochloric acid; filter; and treat filtrate with slight excess of 6M sodium hydroxide. Boil, settle precipitate for 12 hours, filter and dispose (OHM/TADS , 1992).
Treatment: For large spills, neutralize with agricultural lime, crushed limestone, or sodium bicarbonate (AAR, 1987).
Treatment: Adjust pH to 7 before disposal (AAR, 1987).
Treatment: Precipitate beryllium by adding carbon dioxide, lime and use cation exchangers to collect (OHM/TADS , 1992).
Treatment: An aluminum coagulant (220 ppm at pH 6.4) combined with 40 ppm ferric chloride at a pH of 6.4 and 415 ppm lime at pH 11.5 precipitated 95% of the beryllium. The coagulant was collected using media filtration (HSDB , 1992).

SMALL LEAK/SPILL

SMALL DRY SPILL PRECAUTIONS - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 141 (ERG, 2004)
- With clean shovel place material into clean, dry container and cover loosely; move containers from spill area.

LARGE LEAK/SPILL

LARGE SPILL PRECAUTIONS - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 141 (ERG, 2004)
- Dike far ahead of spill for later disposal.

-ENVIRONMENTAL HAZARD MANAGEMENT

POLLUTION HAZARD

Beryllium nitrate sinks and mixes with water (CHRIS , 1992).

Beryllium concentrations less than 0.22 mcg/L were found in analyses of 85% of samples from 15 major river basins in the US (HSDB , 1992).

In US drinking water beryllium concentrations ranged from 0.017 to 0.7 mcg/L with a mean of 0.013 mcg/L (HSDB , 1992).

Water uses threatened include recreation, fisheries, and irrigation (OHM/TADS , 1992).

It is harmful to aquatic life in low concentrations (OHM/TADS , 1992).

This compound may be dangerous if it enters water intakes. Notify operators of water intakes as well as local health and wildlife officials (OHM/TADS , 1992).

AIR: Beryllium nitrate is a toxic air pollutant (OHM/TADS , 1992).

Bioconcentration of 100-fold can occur under chronic exposure conditions, but would not be significant under spill conditions (CHRIS , 1992).

Some potential exists for food chain bioaccumulation (OHM/TADS , 1992).

ENVIRONMENTAL FATE AND KINETICS

OTHER

OTHER
- Beryllium nitrate is fairly unstable in water (OHM/TADS , 1992).
- Some potential exists for food chain bioaccumulation (OHM/TADS , 1992).

ENVIRONMENTAL TOXICITY

At very low concentrations, beryllium nitrate is harmful to aquatic life (CHRIS , 1992).

Contamination in water should not exceed 1.5 ppm for 96 hours to remain below an LC50 for marine life (OHM/TADS , 1992).

A concentration of 5% elemental beryllium in water was non-toxic to fish; a 10% concentration was (OHM/TADS , 1992).

Livestock toxicity: 200 ppm (OHM/TADS , 1992)

Plant toxicity: 0.1 ppm (At an acid pH like a nitrate salt such as beryllium nitrate, it is highly toxic to plants) (OHM/TADS , 1992).

FRESHWATER TOXICITY

Published Values (HSDB , 1992; RTECS , 1992):

LC50 FATHEAD MINNOW: 50 mcg/L/96 hr in soft water
LC50 FATHEAD MINNOW: 20,000 mcg/L in hard water
LC50 BLUEGILL: 1300 mcg/L/96 hrs in soft water
LC50 BLUEGILL: 12,000 mcg/L in hard water
LC50 GOLDFISH: 4800 mcg/L
LC50 FATHEAD MINNOW: 3250 mcg/L
LC50 FLAGFISH: 3530 mcg/L

-PHYSICAL/CHEMICAL PROPERTIES

MOLECULAR WEIGHT

133.03 (Budavari, 1989)

DESCRIPTION/PHYSICAL STATE

Beryllium nitrate is an odorless, white to pale yellow, deliquescent, crystalline solid (AAR, 1987; (Budavari, 1989; HSDB , 1992).

VAPOR PRESSURE

Not Applicable

DENSITY

TEMPERATURE AND/OR PRESSURE NOT LISTED

solid/trihydrate: 1.56 g/cm(3) (CHRIS , 1992; HSDB , 1992)

FREEZING/MELTING POINT

MELTING POINT

60 degrees C (Budavari, 1989)

BOILING POINT

142 degrees C (HSDB , 1992)

FLASH POINT

Not Flammable (CHRIS , 1992)

EXPLOSIVE LIMITS

LOWER

Not Applicable

UPPER

Not Applicable

SOLUBILITY

IN WATER

Beryllium nitrate is very soluble in water (Budavari, 1989; OHM/TADS , 1992).

IN ORGANIC SOLVENTS

It is very soluble in alcohol (Budavari, 1989; OHM/TADS , 1992).

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BERYLLIUM NITRATE

Classification | Information to evaluate chemical incidents

Information to evaluate chemical incidents

Information to evaluate chemical incidents

Information to evaluate chemical incidents