POLYTETRAFLUOROETHYLENE; TEFLON(R)
HAZARDTEXT ®
Information to help in the initial response for evaluating chemical incidents
-IDENTIFICATION
SYNONYMS
POLYTETRAFLUOROETHYLENE; TEFLON(R) ETHYLENE, TETRAFLUORO-, POLYMER AFLON ALGLOFLON ALGOFLON SV ALKATHENE RXDG33 AMIP 15M BALFON 7000 BDH 29-801 CHROMOSORB T DIXON 164 DLX-6000 DUROID 5870 EK 1108GY-A ETHENE, TETRAFLUORO-, HOMOPOLYMER ETHICON PTFE F 103 FBF 74D F 4K20 FLUO-KEM FLUON FLUON CD 1 FLUON CD 023 FLUON CD 042 FLUON G4 FLUON G163 FLUON G201 FLUON GPI FLUON L 169 FLUON L 170 FLUON L 171 FLUON L 169B FLUOROFLEX FLUOROLON 4 FLUOROPAK 80 FLUOROPLAST 4 FLUOROPLAST 4B FLUOROPLAST 4D FLUOROPLAST 4M FLUOROPORE FP 120 F 4MB FN 3 FT-4 FTORLON 4 FTORLON F-4MB FTORLON 4M FTOROPLAST 4 FTOROPLAST 4B FTOROPLAST 4D FTOROPLAST F-4 FTOROPLAST FBF 74D FTOROPLAST F 4MB FTOROPLAST 4K20 FTOROPLAST 4M F 4Zh20 G 163 GORE-TEX HALON G 80 HALON G 183 HALON G 700 HALON TFEG 180 HEYDEFLON HOSTAFLON HOSTAFLON TF HOSTAFLON TF 2026 HOSTAFLON TF 2053 L 169 MOLYKOTE 522 POLIFEN POLITEF POLY(ETHYLENE TETRAFLUORIDE) POLYFENE POLYFLON POLYFLON D1 POLYFLON EK 4108GY POLYFLON EK 1108GY-A POLYFLON F 103 POLYFLON M12 POLYFLON M21 POLYFLON M12A POLYTEF POLYTETRAFLUOROETHENE POLYTETRAFLUOROETHYLENE PTFE PTFE-GM3 SOREFLON 604 SOREFLON 5A T 8A TARFLEN T 5B TE 30 TEFLON TEFLON 5 TEFLON 6 TEFLON 30 TEFLON 110 TEFLON 6C TEFLON K TEFLON T5 TEFLON T 6 TEFLON T 30 TEFLON TFE TETRAFLUOROETHENE HOMOPOLYMER TETRAFLUOROETHENE POLYMER TETRAFLUOROETHYLENE HOMOPOLYMER TETRAFLUOROETHYLENE POLYMERS TETRAN 30 TETRAN PTFE TL 102 TL 115 TL 125 TL 126 TL-R TL-V UNON P VALFLON VELFLON ZITEX H 662-124 ZITEX K 223-122
IDENTIFIERS
USES/FORMS/SOURCES
PTFE is used for vascular grafts, non-stick coatings on cooking and laboratory utensils, protective clothing, reconstructive prostheses, insulation material, molded electrical components and tapes, and lubricant powders (Clayton & Clayton, 1982; (ACGIH, 1986; HSDB , 1997).
POLYTETRAFLUOROETHYLENE (PTFE) is popularly called TEFLON(R), but has many other trade names. It is a grayish-white, opaque, non-flammable, inert, tough plastic found in three physical forms: granular, fine powder, or aqueous dispersions, as well as in final end-use molded or machined solids. It is unaffected by organic solvents and will dissolve only in alkali metals and fluorine under pressure (HSDB , 1997). At temperatures greater than 400 degrees C, toxic pyrolysis products can be formed, including HYDROGEN FLUORIDE, CARBONYL FLUORIDE, CARBON TETRAFLUORIDE, OCTAFLUOROISOBUTYLENE, and CARBON DIOXIDE (HSDB , 1997; Arito & Soda, 1977; p 9). PTFE is an inert substance. Reported health effects have been due to PYROLYSIS PRODUCTS. The most common sources of exposure are WELDING and SMOKING CIGARETTES CONTAMINATED WITH PTFE DUST (HSDB , 1997). Exposure to the decomposition products can be estimated by quantitative determination of FLUORIDE from air samples (ACGIH, 1991). With respect to exposure solely to the dust, 15 mg/m(3) may be tolerated for 8 hours (Anon, 1963).
-CLINICAL EFFECTS
GENERAL CLINICAL EFFECTS
- Editor's Note: An ERG guide with information appropriate to this material does not exist.
ACUTE CLINICAL EFFECTS
- Short-term inhalation of PTFE fumes may cause respiratory irritation, dry cough, shortness of breath, elevated temperature, and pulmonary edema (Evans, 1973; Robbins & Ware, 1964). There has been at least one fatality from acute exposure to PTFE pyrolysis products (Auclair, 1983).
- Rabbits inhaling decomposition products of PTFE developed lung damage (Liang, 1980). Use of aerosol products containing PTFE at room temperature should not release toxic products (Mutschler, 1978).
CHRONIC CLINICAL EFFECTS
- Inhaling PTFE decomposition products can cause POLYMER FUME FEVER, a flu-like condition with chills, fever, chest pain, shortness of breath, headaches, shaking chills, and cough. Symptoms usually disappear within 24 to 48 hours (HSDB , 1997; Adams, 1963; Anon, 1958). Polymer fume fever can also arise from inhalation of PTFE DUST (Makulova, 1970).
- Rats exposed to PTFE fume developed thrombosis and kidney damage (Zook et al, 1983). In rats, carbonyl-fluoride thermally released from PTFE had a cumulative, though reversible, effect and caused fluoride poisoning (Scheel, 1968).
-RANGE OF TOXICITY
MAXIMUM TOLERATED EXPOSURE
- Carcinogenicity Ratings for CAS9002-84-0 :
ACGIH (American Conference of Governmental Industrial Hygienists, 2010): Not Listed EPA (U.S. Environmental Protection Agency, 2011): Not Listed IARC (International Agency for Research on Cancer (IARC), 2016; International Agency for Research on Cancer, 2015; IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, 2010; IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, 2010a; IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, 2008; IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, 2007; IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, 2006; IARC, 2004): 3 ; Listed as: Polytetrafluoroethylene 3 : The agent (mixture or exposure circumstance) is not classifiable as to its carcinogenicity to humans. This category is used most commonly for agents, mixtures and exposure circumstances for which the evidence of carcinogenicity is inadequate in humans and inadequate or limited in experimental animals. Exceptionally, agents (mixtures) for which the evidence of carcinogenicity is inadequate in humans but sufficient in experimental animals may be placed in this category when there is strong evidence that the mechanism of carcinogenicity in experimental animals does not operate in humans. Agents, mixtures and exposure circumstances that do not fall into any other group are also placed in this category.
NIOSH (National Institute for Occupational Safety and Health, 2007): Not Listed MAK (DFG, 2002): Not Listed NTP (U.S. Department of Health and Human Services, Public Health Service, National Toxicology Project ): Not Listed
TOXICITY AND RISK ASSESSMENT VALUES
- EPA Risk Assessment Values for CAS9002-84-0 (U.S. Environmental Protection Agency, 2011):
-STANDARDS AND LABELS
WORKPLACE STANDARDS
- ACGIH TLV Values for CAS9002-84-0 (American Conference of Governmental Industrial Hygienists, 2010):
- AIHA WEEL Values for CAS9002-84-0 (AIHA, 2006):
- NIOSH REL and IDLH Values for CAS9002-84-0 (National Institute for Occupational Safety and Health, 2007):
- OSHA PEL Values for CAS9002-84-0 (U.S. Occupational Safety, and Health Administration (OSHA), 2010):
- OSHA List of Highly Hazardous Chemicals, Toxics, and Reactives for CAS9002-84-0 (U.S. Occupational Safety and Health Administration, 2010):
ENVIRONMENTAL STANDARDS
- EPA CERCLA, Hazardous Substances and Reportable Quantities for CAS9002-84-0 (U.S. Environmental Protection Agency, 2010):
- EPA CERCLA, Hazardous Substances and Reportable Quantities, Radionuclides for CAS9002-84-0 (U.S. Environmental Protection Agency, 2010):
- EPA RCRA Hazardous Waste Number for CAS9002-84-0 (U.S. Environmental Protection Agency, 2010b):
- EPA SARA Title III, Extremely Hazardous Substance List for CAS9002-84-0 (U.S. Environmental Protection Agency, 2010):
- EPA SARA Title III, Community Right-to-Know for CAS9002-84-0 (40 CFR 372.65, 2006; 40 CFR 372.28, 2006):
- DOT List of Marine Pollutants for CAS9002-84-0 (49 CFR 172.101 - App. B, 2005):
- EPA TSCA Inventory for CAS9002-84-0 (EPA, 2005):
LABELS
- NFPA Hazard Ratings for CAS9002-84-0 (NFPA, 2002):
-PERSONAL PROTECTION
SUMMARY
- Editor's Note: An ERG guide with information appropriate to this material does not exist.
PROTECTIVE CLOTHING
- CHEMICAL PROTECTIVE CLOTHING. Search results for CAS 9002-84-0.
-PHYSICAL HAZARDS
FIRE HAZARD
- FLAMMABILITY CLASSIFICATION
- NFPA Flammability Rating for CAS9002-84-0 (NFPA, 2002):
- FIRE CONTROL/EXTINGUISHING AGENTS
- Editor's Note: An ERG guide with information appropriate to this material does not exist.
- NFPA Extinguishing Methods for CAS9002-84-0 (NFPA, 2002):
EVACUATION PROCEDURES
- Editor's Note: An ERG guide with information appropriate to this material does not exist.
- AIHA ERPG Values for CAS9002-84-0 (AIHA, 2006):
- DOE TEEL Values for CAS9002-84-0 (U.S. Department of Energy, Office of Emergency Management, 2010):
Listed as Tetrafluoroethylene, polymer TEEL-0 (units = ppm): 3.5 TEEL-1 (units = ppm): 10 TEEL-2 (units = ppm): 60 TEEL-3 (units = ppm): 350 Definitions: TEEL-0: The threshold concentration below which most people will experience no adverse health effects. TEEL-1: The airborne concentration (expressed as ppm [parts per million] or mg/m(3) [milligrams per cubic meter]) of a substance above which it is predicted that the general population, including susceptible individuals, could experience notable discomfort, irritation, or certain asymptomatic, nonsensory effects. However, these effects are not disabling and are transient and reversible upon cessation of exposure. TEEL-2: The airborne concentration (expressed as ppm or mg/m(3)) of a substance above which it is predicted that the general population, including susceptible individuals, could experience irreversible or other serious, long-lasting, adverse health effects or an impaired ability to escape. TEEL-3: The airborne concentration (expressed as ppm or mg/m(3)) of a substance above which it is predicted that the general population, including susceptible individuals, could experience life-threatening adverse health effects or death.
- AEGL Values for CAS9002-84-0 (National Research Council, 2010; National Research Council, 2009; National Research Council, 2008; National Research Council, 2007; NRC, 2001; NRC, 2002; NRC, 2003; NRC, 2004; NRC, 2004; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; 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62 FR 58840, 1997; 65 FR 14186, 2000; 65 FR 39264, 2000; 65 FR 77866, 2000; 66 FR 21940, 2001; 67 FR 7164, 2002; 68 FR 42710, 2003; 69 FR 54144, 2004):
- NIOSH IDLH Values for CAS9002-84-0 (National Institute for Occupational Safety and Health, 2007):
CONTAINMENT/WASTE TREATMENT OPTIONS
-PHYSICAL/CHEMICAL PROPERTIES
-REFERENCES
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