N-METHYLPYRROLIDONE
HAZARDTEXT ®
Information to help in the initial response for evaluating chemical incidents
 -IDENTIFICATION
SYNONYMS
N-METHYLPYRROLIDONE 1-METHYL-2-PYRROLIDINONE 1-METHYL-2-PYRROLIDONE 1-METHYL-5-PYRROLIDINONE 1-METHYLAZACYCLOPENTAN-2-ONE 1-METHYLPYRROLIDINONE 1-METHYLPYRROLIDONE 2-PYRROLIDINONE, 1-METHYL- M-PYROL METHYLPYRROLIDONE N-METHYL-2-PYRROLIDINONE N-METHYL-2-PYRROLIDONE N-METHYL-alpha-PYRROLIDINONE N-METHYL-alpha-PYRROLIDONE N-METHYL-gamma-BUTYROLACTAM N-METHYLPYRROLIDINONE NMP
IDENTIFIERS
USES/FORMS/SOURCES
It is used as a solvent, pigment dispersant, chemical intermediate, in petroleum processing, and as a spinning agent for polyvinyl chloride (HSDB , 1995). It is also used as a chemical reaction medium, as a solvent for coatings, and in stripping and cleaning microelectronic components (Clayton & Clayton, 1994).
N-methylpyrrolidone (NMP) is a methylated heterocyclic compound. It is a colorless to light yellow liquid with a mild amine-like odor, and is soluble or miscible with water, ether, acetone, chloroform, benzene, and ethyl acetate (HSDB , 1995; Clayton & Clayton, 1994). It can dissolve many organic and inorganic compounds (HSDB , 1995).
-CLINICAL EFFECTS
GENERAL CLINICAL EFFECTS
- Editor's Note: An ERG guide with information appropriate to this material does not exist.
ACUTE CLINICAL EFFECTS
- With an acute oral LD50 of 4320 mg/kg in rats, N-methylpyrrolidone has low acute toxicity (Clayton & Clayton, 1994).
- N-methylpyrrolidone is a moderate eye irritant in rabbits in the Standard Draize test (RTECS , 1995). It has also been reported to be a severe eye irritant (HSDB , 1995). It was not a skin irritant or sensitizer in guinea pigs (Clayton & Clayton, 1994).
- Rats injected intravenously with 200 mg/kg N-methylpyrrolidone developed hyperglycemia; a dose of 500 mg/kg produced hypotension and cardiac arrhythmias (HSDB , 1995).
- N-methylpyrrolidone has been reported to inhibit acetylcholinesterase in vitro (HSDB , 1995; Karadsheh et al, 1991). The human clinical significance of this finding is unclear.
- In rats, approximately 70 percent of a total dose was eliminated in the urine within 12 hours (HSDB , 1995) Wells & Digenis, 1988).
CHRONIC CLINICAL EFFECTS
- Occupational exposure to N-methylpyrrolidone at airborne levels as low as 0.7 ppm has been associated with chronic eye irritation and headaches; airborne concentrations of 49 to 83 ppm were unbearable (Beaulieu & Schmerber, 1991; Clayton & Clayton, 1994). Ten of 12 workers developed skin irritation (acute irritant contact dermatitis) after working with N-methylpyrrolidone for 2 days (Leira et al, 1992).
- Reversible bone marrow depression, increased neutrophils, pulmonary edema, focal interstitial pneumonitis, and atrophy of lymphoid and thymus tissue were seen in rats exposed to aerosols at airborne concentrations up to 1 mg/L for 6 hours/day for 4 weeks (HSDB , 1995; Lee et al, 1987).
- No significant effects were seen in dogs exposed to dietary levels as high as 250 mg/kg/day for 13 weeks (HSDB , 1995; Becci et al, 1983). In a subchronic exposure study, no adverse effects were seen in rats exposed to a saturated atmosphere of N-methylpyrrolidone (approximately 370 ppm) (Clayton & Clayton, 1994).
-RANGE OF TOXICITY
MAXIMUM TOLERATED EXPOSURE
- Carcinogenicity Ratings for CAS872-50-4 :
ACGIH (American Conference of Governmental Industrial Hygienists, 2010): Not Listed EPA (U.S. Environmental Protection Agency, 2011): Not Listed IARC (International Agency for Research on Cancer (IARC), 2016; International Agency for Research on Cancer, 2015; IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, 2010; IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, 2010a; IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, 2008; IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, 2007; IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, 2006; IARC, 2004): Not Listed NIOSH (National Institute for Occupational Safety and Health, 2007): Not Listed MAK (DFG, 2002): Not Listed NTP (U.S. Department of Health and Human Services, Public Health Service, National Toxicology Project ): Not Listed
TOXICITY AND RISK ASSESSMENT VALUES
- EPA Risk Assessment Values for CAS872-50-4 (U.S. Environmental Protection Agency, 2011):
-STANDARDS AND LABELS
WORKPLACE STANDARDS
- ACGIH TLV Values for CAS872-50-4 (American Conference of Governmental Industrial Hygienists, 2010):
- AIHA WEEL Values for CAS872-50-4 (AIHA, 2006):
- NIOSH REL and IDLH Values for CAS872-50-4 (National Institute for Occupational Safety and Health, 2007):
- OSHA PEL Values for CAS872-50-4 (U.S. Occupational Safety, and Health Administration (OSHA), 2010):
- OSHA List of Highly Hazardous Chemicals, Toxics, and Reactives for CAS872-50-4 (U.S. Occupational Safety and Health Administration, 2010):
ENVIRONMENTAL STANDARDS
- EPA CERCLA, Hazardous Substances and Reportable Quantities for CAS872-50-4 (U.S. Environmental Protection Agency, 2010):
- EPA CERCLA, Hazardous Substances and Reportable Quantities, Radionuclides for CAS872-50-4 (U.S. Environmental Protection Agency, 2010):
- EPA RCRA Hazardous Waste Number for CAS872-50-4 (U.S. Environmental Protection Agency, 2010b):
- EPA SARA Title III, Extremely Hazardous Substance List for CAS872-50-4 (U.S. Environmental Protection Agency, 2010):
- EPA SARA Title III, Community Right-to-Know for CAS872-50-4 (40 CFR 372.65, 2006; 40 CFR 372.28, 2006):
Listed as: N-Methyl-2-pyrrolidone Effective Date for Reporting Under 40 CFR 372.30: 1/1/95 Lower Thresholds for Chemicals of Special Concern under 40 CFR 372.28:
- DOT List of Marine Pollutants for CAS872-50-4 (49 CFR 172.101 - App. B, 2005):
- EPA TSCA Inventory for CAS872-50-4 (EPA, 2005):
LABELS
- NFPA Hazard Ratings for CAS872-50-4 (NFPA, 2002):
-PERSONAL PROTECTION
SUMMARY
- Editor's Note: An ERG guide with information appropriate to this material does not exist.
PROTECTIVE CLOTHING
- CHEMICAL PROTECTIVE CLOTHING. Search results for CAS 872-50-4.
-PHYSICAL HAZARDS
FIRE HAZARD
- FLAMMABILITY CLASSIFICATION
- NFPA Flammability Rating for CAS872-50-4 (NFPA, 2002):
- FIRE CONTROL/EXTINGUISHING AGENTS
- Editor's Note: An ERG guide with information appropriate to this material does not exist.
- NFPA Extinguishing Methods for CAS872-50-4 (NFPA, 2002):
EVACUATION PROCEDURES
- Editor's Note: An ERG guide with information appropriate to this material does not exist.
- AIHA ERPG Values for CAS872-50-4 (AIHA, 2006):
- DOE TEEL Values for CAS872-50-4 (U.S. Department of Energy, Office of Emergency Management, 2010):
- AEGL Values for CAS872-50-4 (National Research Council, 2010; National Research Council, 2009; National Research Council, 2008; National Research Council, 2007; NRC, 2001; NRC, 2002; NRC, 2003; NRC, 2004; NRC, 2004; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; 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National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; 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62 FR 58840, 1997; 65 FR 14186, 2000; 65 FR 39264, 2000; 65 FR 77866, 2000; 66 FR 21940, 2001; 67 FR 7164, 2002; 68 FR 42710, 2003; 69 FR 54144, 2004):
- NIOSH IDLH Values for CAS872-50-4 (National Institute for Occupational Safety and Health, 2007):
CONTAINMENT/WASTE TREATMENT OPTIONS
-PHYSICAL/CHEMICAL PROPERTIES
-REFERENCES
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